Product ID:CALCIUM CHLORIDE
MSDS Date:08/07/1996
FSC:6810
NIIN:00-658-4999
MSDS Number: CFMQW

VAN WATERS AND ROGERS

2256 JUNCTION AVE
SAN JOSE, CA 95131
US

Emergency Phone: 408-435-8700/800-424-9300(CHEMTREC)

Info Phone: 408-435-8700

Cage: 0STM5

VOPAK USA INC

KIRKLAND, WA 98033-7357 US

Telephone: 425-889-3400/425-889-3617

Cage: 0STM5

HEAVY METALS

Fraction By Weight: 0.002%

LEAD (SARA 313) (CERCLA) (0.001% MAX)

CAS: 7439-92-1

RTECS: OF7525000

Fraction By Weight: 0.001%

OSHA PEL SEE 1910.1025

ACGIH TLV: 0.05MG/M3, A3; 9596

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CALCIUM CHLORIDE

CAS: 10043-52-4

RTECS: EV9800000

LD50 LC50 Mixture:ORLA RAT LD50:1000MG/KG.
Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:WARNING!CAUSES IRRIT.MAY BE HARMFUL IF
SWALLOWED.INHAL:GRANULAR MATL DOESNT PRESENT SER INHAL HAZ BUT DUST
MAY PRODUCE UPPER RESP TRACT IRRIT.INGEST:MAY CAUSE SERIOUS IRRIT
OF MUC MEMB DUE TO HEAT OF HYDROLYSIS.LG MATS CAUSE GI
UPSET,VOMIT,ABD PAIN.SKIN:IRRIT,BURNS ON MOIST SKIN DUE TO HEAT OF
HYDROLYSIS.(SIGN/SYMPT)
Effects of Overexposure:HEALTH:EYE:HAZ MAY BE EITHER MECHANICAL
ABRASION OR MORE SERIOUS BURNS FROM HEAT OF HYDROLYSIS & CHLORIDE
IRRIT.CHRONIC:NO INFO FOUND.
Medical Cond Aggravated by Exposure:CONTACT MAY AGGRAVATE ANY EXISTING
SKIN CONDITIONS.

First Aid:INHAL:REMOVE TO FRESH AIR.GET MED ATTN FOR ANY BREATH
DIFFICULTY.INGEST:GIVE WATER OR MILK TO DRINK ASAP.CALL DR
IMMED.NEVER GIVE ANYTHING BY MOUTH IF UNCONSC.SKIN:REMOVE ANY
CONTAM CLOTH.WIPE OFF EXC ESS FROM SKIN.WASH SKIN W/SOAP/WATER FOR
@LEAST 15MINS.GET MED ATTN IF IRRIT DEVELOPS/PERSISTS.EYE:WASH
W/PLENTY OF WATER FOR @LEAST 15MINS LIFTING LOWER/UPPER EYELIDS.GET
MED ATTN IMMED.

Flash Point:NP
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NP
Upper Limits:NP
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE.
Fire Fighting Procedures:IN EVENT OF FIRE WEAR FULL PROTECTIVE
CLOTH/NIOSH APPROV SCBA W/FULL FCPIECE OPERATED IN PRESSURE
DEAMAND/OTHER +PRESSURE MODE.@HI TEMPS/WHEN MOISTENED(SUPPLEM)
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE FIRE OR EXPLOSIOIN
HAZARD.

Spill Release Procedures:SWEEP,SCOOP,PICK UP SPILL MATL.COLLECTED WASTE
MAY BE TRANSFERRED TO CLOSED WATER-PROOF NON-METAL CNTNR & SENT OT
APPROVED WASTE DISPO FACILITY.ENSURE COMPLIANCE W/LOC/STATE/FED
REGS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP TIGHTLY CLSD CNTNR STORE IN COOL
DRY VENTI AREA.PROTECT AGAINST PHYS DMG.MOIST CACL2,CONC SOLN CAN
CORRODE STEEL.AVOID EYE/SKIN/CLOTH CONTACT.
Other Precautions:WHEN EXPO TO ATM CACL2 SILL ABSORB WATER & FORM
SOLN.MAINTAIN GOOD HOUSEKEEPING IN WORK AREA.DUST DISOSITS ON
FLOORS & OTHER SURFACES MAY PICK UP MOISTURE & CUSE SURFACES TO
BECOME SLIPPERY & PRESENT SAFETY HAZARD.

Respiratory Protection:(NIOSH APPROVED).IF TLV EXCEECED DUST/MIST RESP
W/CHEM GOGG MAY BE WORN IN GENERAL UP TO TEN TIMES THE TLV.CONSULT
RESPIRATOR SUPPLIER FOR LIMITATIONS.ALTERNATIVELY SUPPLIED AIR FULL
FACEPIECE RESPIRA TOR OR AIRLINED HOOD MAY BE WORN.
Ventilation:LOC &/OR GEN EXHAU SYST RECOMMENDED-KEEP WORKER EXPO BEL
AEL.LOC EXHAU PREF-CAN CNTRL CONTAM EMISSIONS @SOURCE,(SUPPLEM)
Protective Gloves:PROTECTIVE GLOVES,CLEAN BODY-COVER CLOTH
Eye Protection:CHEM SAF GOGG &/OR FULL FCSHIELD
Other Protective Equipment:CONTACT LENSES SHOULD NOT BE WORN WHEN
WORKING W/THIS MATL.MAINTAIN EYEWASH FOUNTAIN,QUICK-DRENCH FACILIT
IN WORKAREA.
Work Hygienic Practices:WASH THOROUGHLY AFT HNDLG.
Supplemental Safety and Health
FIREFIGHT:UNDER FIRE CONDITIONS CACL2 MAY PRODUCE TOXIC/IRRIT FUMES OF
CACL2/HCL. DECOMPO PROD:@ELEVATED TEMPS. INCOMPAT:CACL2
SOLNS.AL(&ALLOYS)&YELLOW BRASS WILL BE ATTACHED BY CACL2.
VENTI:PREVENT D ISPERSION INTO GEN WORKAREA.REF:ACGIH "INDUSTRIAL
VENTI,MANUAL OF RECOMMENDED PRACTICES"MOST RECENT EDITION.

HCC:N1
Boiling Pt:B.P. Text:>2912F,>160
Melt/Freeze Pt:M.P/F.P Text:1422F,772C
Decomp Temp:Decomp Text:NP
Vapor Pres:NO INFO
Vapor Density:NO INFO
Spec Gravity:2.15
pH:NP
Viscosity:NP
Evaporation Rate & Reference:NO INFO FOUND
Solubility in Water:FREELY SOLUBLE,EXOTH
Appearance and Odor:WHITE OR GRAY-WHITE GRANULES,ODORLESS
Percent Volatiles by Volume:NP
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
METHYL VINYL ETHER,H2O,ZN,BR,FL3,LIME/BORIC ACID MIX,BACL3,2-FURAN
PERCARBOXYLIC ACID.METALS SLOWLY CORRODE IN AQU(SUPP)
Stability Condition to Avoid:SUBSTANCE WILL PICK UP MOISTURE FROM AIR &
GO INTO SOLUTION IF EXPO IN OPN CNTNRS.WATER SOLN OF THIS MATL IS
ACIDIC.
Hazardous Decomposition Products:EMITS TOXIC CHLORINE FUMES WHEN HEATED
TO DECOMPO.MAY FORM HCL IN PRESENCE OF SULFURIC OR PHOSPHORIC ACIDS
OR W/H2O(SUP)

Waste Disposal Methods:APPROVED WASTE DISPOSAL FACILITY.PRODUCT
MAYCONTAIN CHEM KNOWN TO STATE OF CALIFORNIA TO CAUSE BIRTH
DEFECTS/OTHER REPRODUCTIVE HARM:HEAVY METALS 0.002%MAX,LEAD
0.001%MAX.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.